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Crystal structure and conformation of the 3'-O-methyl derivative in 1-.beta.-D-arabinofuranosylcytosine

โœ Scribed by Birnbaum, G. I.; Darzynkiewicz, E.; Shugar, D.


Book ID
126824667
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
561 KB
Volume
97
Category
Article
ISSN
0002-7863

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Methyl 6-deoxy-2,3-0-isopropylidene-a-D-manno-heptofuranoside (9) has been synthesised from the acetyliron complex 2 by a sequence of reactions involving deprotonation of 2, its reaction with aldehyde 5, decomplexation, isolation of 7, and reduction to 9. Compound 9 crystallises in the orthorbombic