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Crystal structure and cation transport properties of the ortho - diphosphates Na7(MP2O7)4PO4 (M = Al, Cr, Fe)

✍ Scribed by M. de la Rochère; A. Kahn; F. d'Yvoire; E. Bretey

Book ID
113186926
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
423 KB
Volume
20
Category
Article
ISSN
0025-5408

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Crystal Structure and Cation Transport P
Crystal Structure and Cation Transport Properties of the Layered Monodiphosphates: Li9M3(P2O7)3(PO4)2(M=Al, Ga, Cr, Fe)
✍ S Poisson; F d'Yvoire; NGuyen-Huy-Dung; E Bretey; P Berthet 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 563 KB

A new series of isotypic monodiphosphates of general formula Li 9 M 3 (P 2 O 7 ) 3 (PO 4 ) 2 with M ‫؍‬ Al, Ga, Cr, Fe was synthesized by flux methods. The crystal structure of the aluminum and iron members is described here. They crystallize in the trigonal space group P3 c1 with a ‫؍‬ 9.553(1), c