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Crystal structure analysis of enantiomerically pure (+) and (−) β-hexabromocyclododecanes

✍ Scribed by Norbert V. Heeb; W. Bernd Schweizer; Peter Mattrel; Regula Haag; Martin Kohler


Book ID
116359030
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
360 KB
Volume
66
Category
Article
ISSN
0045-6535

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The preparation of enantiomerically pure /3,~epoxyesters was achieved by chemoselective opening of &hydroxybutanoli&s with trimethylsilyliodide followed by cyclisation of the resulting iodohydrins with silver oxide. The reaction of these epoxyesters with lithio or magnesiocuprates ajorded stereochem