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Crystal structural properties of a pinwheel compound: [36](1,2,3,4,5,6)cyclophane

✍ Scribed by Mikio Yasutake; Youichi Sakamoto; Satoru Onaka; Katsuya Sako; Hitoshi Tatemitsu; Teruo Shinmyozu

Book ID
104210935
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
216 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the crystal structures of 3 6 cyclophane 1 and the 1:TCNQ (1:1) complex, the cyclophane moiety is observed as the D 6h structure because of the disorder of the molecules with C 6h symmetry. In contrast, the C 6h structure is observed in the crystals of the 1:TCNQ-F 4 (1:1) complex, and the complex shows an alternating donor-acceptor stacking with partial donor-acceptor overlap.

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✍ Youichi Sakamoto; Naomi Miyoshi; Prof. Dr. Teruo Shinmyozu πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 268 KB πŸ‘ 1 views

Cyclophane 1, a compound we have long sought""' and one of the final target molecules in the field of [3,3]cyclophane chemistry, has finally been synthesized and characterized. We expect 1 to have fascinating chemical and structural features. A photochemical isomerization of 1 to the propella[3,]prt