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Crystal solvates of porphyrins and metalloporphyrins

✍ Scribed by Antina, E. V.; V’yugin, A. I.

Book ID: 118725535
Publisher: Springer
Year: 2012
Tongue: English
Weight: 219 KB
Volume: 82
Category: Article
ISSN: 1070-3632
DOI: 10.1134/s1070363212070201

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Suhstituent effects an complex formation between variously substituted metallodeuteroporphyrins with filled 12~ orbitals and extraplanar hgand(s) ean be correlated by Hammett freeenergy plots. The slopes of these plots are positive and the correlation is high with substituent constants typical of re