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Crystal lattice control of unimolecular photorearrangements. Differences in cyclohexenone photochemistry in solution and the solid state. Solution results

✍ Scribed by Appel, Wolfgang K.; Greenhough, Trevor J.; Scheffer, John R.; Trotter, James; Walsh, Leueen

Book ID
126140864
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
421 KB
Volume
102
Category
Article
ISSN
0002-7863

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## Abstract The photochemistry of 11,12‐bis(aminomethyl)‐9,10‐dihydro‐9,10‐ethenoanthracene (4) was investigated in solution and in the solid state. Direct irradiation of 4 gave the singlet state photoproduct 5, whereas the triplet derived photoproduct could only be obtained by irradiating the bis(