Crystal growth of alkali metal tungsten brozes MxWO3 (M K, Rb, Cs), and their optical properties
✍ Scribed by A. Hussain; R. Gruehn; C.H. Rüscher
- Book ID
- 117623230
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 699 KB
- Volume
- 246
- Category
- Article
- ISSN
- 0925-8388
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Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100±140 °C during 3±12 h. X-ray single crystal structures for isotypic I and II reveal the presence of
Ternary indium (III) phosphates with three-dimensional frameworks, [M 3 In(PO 4 ) 2 ] n (M ¼ K, n ¼ 10; M ¼ Rb, n ¼ 2), are found and firstly reported in this paper. These compounds have been obtained by high temperature solid-state reactions and their crystal structures have been determined by sing