Crystal form and structure of some isonitrosoacetanilide derivatives
✍ Scribed by X. Solans; M. Aguiló; M. Font-Altaba
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 635 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-0248
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## Abstract The addition of thiosemicarbazones 1 to α‐halo acids 2 is shown to give 2‐hydrazino‐2‐thiazolin‐4‐ones 3 and not 3‐substituted 2‐imino‐3‐(methyleneimino)thiazolidin‐4‐ones 4. The independent synthesis of 2‐thiazolin‐4‐one derivatives 3 is also described.
Single crystals of a new form of \(\mathrm{K}_{2} \mathrm{FeF}_{5}\) have been grown by hydrothermal synthesis in concentrated HF solutions. The structure is established from single crystal X-ray diffraction data: space group Pbam, \(Z=8, a=7.3591\) (4) \(\AA, b=23.0897\) (10) \(\AA\), and \(c=5.705