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Crystal field and exchange effects in rare earth semiquinone complexes

✍ Scribed by Andrea Dei; Dante Gatteschi; Jacques Pécaut; Sandrine Poussereau; Lorenzo Sorace; Kira Vostrikova


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
164 KB
Volume
4
Category
Article
ISSN
1387-1609

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Crystal field strength: Angular overlap
✍ M. Faucher; D. Garcia; C.K. Jørgensen 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 390 KB

An expression for the crystal field strength is defined in terms of one-electron energies and crystal field parameters. The relative contribution of kinetic energy and Coulombic interaction in ligand field effects is analyzed. The angular overlap model is applied to 11 rareearth or rareearthdoped co