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Crystal engineering and [C-H •••O] hydrogen bonds at the organic/inorganic interface. The bi-continuous hybrid composite, κ(2/3-3)-(EDT-TTF)8[Ca(H2O)4]2(TeW6O24)· 7H2O2

✍ Scribed by Kamal Boubekeur; Régis Riccardi; Patrick Batail; Canadell Enric


Book ID
104430066
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
607 KB
Volume
1
Category
Article
ISSN
1387-1609

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The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat