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Crystal-chemical functions of [Hg2]2+and [Hg3]4+groups in inorganic structures

✍ Scribed by S. V. Borisov; S. A. Magarill; G. V. Romanenko; N. V. Pervukhina

Book ID: 110658761
Publisher: SP MAIK Nauka/Interperiodica
Year: 2000
Tongue: English
Weight: 871 KB
Volume: 41
Category: Article
ISSN: 0022-4766
DOI: 10.1007/bf02741592

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The reactions of HgS and HgSe with HgI 2 yield Hg 3 S 2 I 2 and Hg 3 Se 2 I 2 , respectively. Orange crystals of Hg 3 S 2 I 2 and light red crystals of Hg 3 Se 2 I 2 are formed in evacuated glass ampoules at 2603C in yields of 50% as the only crystalline compounds. The crystal structures have been s