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Crystal and molecular structures of the binuclear complex of rhodium(III) chloride with selenium dichloride and the complex of iridium(III) chloride with sulfur dichloride and tetrachloride

✍ Scribed by V. B. Rybakov; L. A. Aslanov; S. V. Volkov; A. V. Grafov; V. I. Pekhn'o; Z. A. Fokina


Publisher
SP MAIK Nauka/Interperiodica
Year
1992
Tongue
English
Weight
307 KB
Volume
33
Category
Article
ISSN
0022-4766

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6,4, 4, perchlorate (2 a) was synthesized via one-step cyclocondensation from bis(N,N'-dimethylethylenediamine-copper(II) perchlorate, formaldehyde and malonic acid. Anion exchange yielded the analogous copper(II) chloride (2 b) and iodide (2 c) complexes. Crystal structures of 2 aΒ±2 c show a sq