## Abstract Organotin tropolonato complexes of the type R~3~Sn(trop) 1 [R = Bu (b), Ph (c)], R~2~Sn(trop)~2~ 2 [R = Me (a), Bu (b), Ph (c)] and RSn(trop)~3~ 3 [R = Bu (b), Ph (c)] were studied by single‐crystal X‐ray diffraction (1c, 2a,b, 3b), ^13^C and ^119^Sn MAS NMR and ^119^Sn NMR in solution.
✦ LIBER ✦
Crystal and molecular structures of some six-coordinate tin(IV) halogeno complexes with phosphorus-containing ligands
✍ Scribed by Andrei S. Batsanov; Robert M. K. Deng; Keith B. Dillon; Andrés E. Goeta; Judith A. K. Howard; James Meldrum; Philippa K. Monks; Horst Puschmann; Helena J. Shepherd
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 277 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1042-7163
- DOI
- 10.1002/hc.20525
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## Abstract The five‐coordinate compounds [MHCl(CO)(P__i__Pr~3~)~2~] (where 1a: M = Ru; 1b: M = Os) react with P__i__Pr~2~R\* [where R\* = CH(Me)Ph] to give the octahedral complexes __mer__‐[MHCl(CO)(P__i__Pr~2~R\*)~3~] (6 and 7). The lability of the phosphane __trans__ to the hydride is illustrate