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Crystal and molecular structures of new fullerides, (Ph4P)2C60Hal (Hal=Br or I) and (Ph4As)2C60Cl

✍ Scribed by V. V. Gritsenko; O. A. Dyachenko; G. V. Shilov; N. G. Spitsyna; E. B. Yagubskii


Publisher
Springer
Year
1997
Tongue
English
Weight
421 KB
Volume
46
Category
Article
ISSN
1573-9171

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Electronic and vibrational spectroscopy were used to study the electronic processes in charge-transfer complexes of fullerene and tetraphenylphosphonium or tetraphenylarsenium halides. These fully ionic crystalline complexes feature the occurrence of C60 monoanions and the onset of charged phonon be