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Crystal and molecular structure of [W(CH2PMe3)(CO)2Cl(PMe3)3][CF3SO3], a seven-coordinate tungsten(II) complex produced by transfer of a trimethylphosphine to the W:CH2 system

✍ Scribed by Churchill, Melvyn Rowen.; Wasserman, Harvey J.

Book ID: 126781408
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 533 KB
Volume: 21
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00141a011

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop