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Crystal and molecular structure of dichlorobis(nitrosobenzene)palladium(II), a nitrogen-bonded arylnitrosometal complex

✍ Scribed by Little, R. G.; Doedens, Robert J.


Book ID
126922024
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
557 KB
Volume
12
Category
Article
ISSN
0020-1669

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The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2H)-thione-5-one (AMTTO, 1) with palladium(II) chloride in acetonitrile/methanol leads to the N,S-coordinated complex [Pd(g 2 -AMTTO-N,S)Cl 2 ] Β΄CH 3 OH (2). 2 has been characterized by IR and MS techniques. The ligand 1 and the complex 2 were also i