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Crystal and molecular structure of [(C6H5)3Sb]3CuCl·CHC13

✍ Scribed by Arnold L. Rheingold; Mark E. Fountain

Publisher
Springer
Year
1984
Tongue
English
Weight
350 KB
Volume
14
Category
Article
ISSN
1572-8854

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Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi