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Crystal and molecular structure of bis(triphenyylphosphine)tetrakis(dimethylglyoximato)dirhodium. Length of a rhodium(II)-to-rhodium(II) single bond

✍ Scribed by Cotton, F. Albert; Caulton, Kenneth G.


Book ID
125981975
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
621 KB
Volume
93
Category
Article
ISSN
0002-7863

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Red, diamagnetic di(phthalocyaninato(2-)rhodium(II)), [( Rhpc ^2βˆ’^)~2~] is prepared by thermal decomposition of acidophthalocyaninatorhodium(III) or di(acido)phthalocyaninatorhodates(III) in inert, high boiling solvents or under reduced pressure at T < 350Β° C . It is insoluble in most common solvent