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Crystal and Molecular Structure of 6α-Methyl-3,20-Dioxo-5β-Pregnan-17α-yl Acetate

✍ Scribed by Dr. D. Scharfenberg-Pfeiffer; J. Wenzel; J. Weiland; M. Bohl


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
328 KB
Volume
26
Category
Article
ISSN
0232-1300

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CH,(18) + 14-CH3; 2.07, s CH,( 4) (CDCI,);not yet crystalli~ed]~). Finally, 8 was converted by catalytic hydrogenation [5%-Pd/C in ethanol/triethylamine; + 11 and cyclisation [HCl in acetic acid] into 3-oxo-17~-acetoxy-14a-methyl-A4-8a,9B,lOa,13a-estrene (12) [m.p. 86-88'; -[ U ] D = + 1' (CHC1,).

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✍ Dr. D. Scharfenberg-Pfeiffer; R. Megges; E. Höhne; H. Stopsack 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 246 KB

Crystal and Molecular Structure of 17a,21-Dihydroxy-l,4-Pregnadiene-3,2O-Dione The title compound 17~,21-dihydroxy-l,4-pregnadiene-3,20-dione crystalIizes in the orthorhombic space group P 212121 with four molecules in the unit cell and the lattice parameters a = 7.727, b = 10.095, c = 22.876 A. The