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Crystal and molecular structure, hydrogen bond and electrostatic interactions of bis(1-methylisonicotinate)hydrogen perchlorate studied by X-ray diffraction, DFT calculations, FT-IR, Raman and NMR spectroscopes

โœ Scribed by M. Szafran; A. Katrusiak; Z. Dega-Szafran


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
482 KB
Volume
880
Category
Article
ISSN
0022-2860

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Crystal and molecular structure, hydroge
โœ M. Szafran; A. Katrusiak; Z. Dega-Szafran ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 577 KB

The crystals of bis(homarine)hydrogen perchlorate, (HOM) 2 HAEClO 4 , (1) are orthorhombic, space group C2/c, with a pair of HOM molecules bridged by a symmetrical OAEHAEO hydrogen bond of 2.480(3) A หš. In the homoconjugated cation, (HOMAEHAEHOM) + , the H-bonded proton is in centre of inversion. Th