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Crystal and Magnetic Structure of PrCaCrO4

✍ Scribed by J. Romero de Paz; M.T. Fernández-Dı́az; J. Hernández Velasco; R. Sáez Puche; J.L. Martı́nez


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
177 KB
Volume
142
Category
Article
ISSN
0022-4596

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✦ Synopsis


The crystal and magnetic structures of PrCaCrO 4 have been characterized by high-resolution neutron diffraction. The structure is described as orthorhombic with space group Bmab and lattice parameters a ‫؍‬ 5.3909(3) A > , b ‫؍‬ 5.3999(3) A > , and c ‫؍‬ 11.9932(5) A > at 200 K. The antiferromagnetic ordering in the Cr 3؉ sublattice is explained on the basis of a propagation vector k ‫؍‬ 0 and a collinear structure, described within a symmetry mode G x and a magnetic moment of 2.38(9) B at 1.5 K. The Ne´el temperature is around 180 K from both neutron diffraction and magnetic susceptibility measurements.


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