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Crucial Role of the Ligand of Silyl Lewis Acid in the Mukaiyama Aldol Reaction.

✍ Scribed by Kazuaki Ishihara; Yukihiro Hiraiwa; Hisashi Yamamoto

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

πŸ“œ SIMILAR VOLUMES

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## Abstract The Lewis acidity of various silyl triflates was quantified by utilizing [D~5~]pyridine as a ^2^H NMR spectroscopy probe. The chemical shifts of the ^2^H NMR signals for pyridine–silyl adducts are reported. The rate constants of silyl triflate catalyzed Diels–Alder reactions were determ