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Crown ethers in inorganic chemistry. Preparation and characterization of the Group 6 pentacarbonyl hydroxides and fluorides

โœ Scribed by Cihonski, John L.; Levenson, Robert A.


Book ID
126114882
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
573 KB
Volume
14
Category
Article
ISSN
0020-1669

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๐Ÿ“œ SIMILAR VOLUMES


18-Crown-6 and Titanium Tetrafluoride โˆ’
โœ T.ย Stanley Cameron; Andreas Decken; Evgenyย G. Ilyin; Grigoriย B. Nikiforov; Jack ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 181 KB ๐Ÿ‘ 1 views

## Abstract Reaction of TiF~4~ and 18โ€crownโ€6 in MeCN affords the molecular complex [(__cisโ€__TiF~4~)~2~(18โ€crownโ€6)] (1) only. Water and THF displace the 18โ€crownโ€6 in the tetrafluoro complex 1, with the formation of __cisโ€__TiF~4~L~2~. The complex __cisโ€__TiF~4~(H~2~O)~2~ and 18โ€crownโ€6 form [{__