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Crown ethers based on bis(benzimidazol-2-yl)alkanes and 1,2-bis(benzimidazol-2-ylsulfanyl)ethane

✍ Scribed by Yu. E. Ivanov; D. E. Stepanov; A. A. Yavolovskii; O. V. Shishkin; V. V. D’yakonenko; G. L. Kamalov


Book ID
114993550
Publisher
Springer
Year
2012
Tongue
English
Weight
203 KB
Volume
82
Category
Article
ISSN
1070-3632

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The coordination geometry of the Co II atom in the title complex, [Co(NCS) 2 (C 16 H 14 N 4 )] or [Co(NCS) 2 (dbz)], where dbz is bis(benzimidazol-2-yl)ethane, is distorted tetrahedral; the Co II atom is coordinated by two N atoms from one dbz molecule and two N atoms from two monodentate NCS À anio

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The supramolecular entities formed by five polybenzimidazolylmethanes, bis(2-tert-butylbenzimidazol-1-yl)methane 2, bis(2-(adamant-1-yl)benzimidazol-1-yl)methane 3, tris(2-ethylbenzimidazol-1-yl)methane 4, tris(2-isopropyl-benzimidazol-1-yl) methane 5, and tris(2-chlorobenzimidazol-1-yl)methane 6 ha