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Crown Ethers as Catalysts in Reactions of Carbanions and Halocarbenes

โœ Scribed by Doz. Dr. M. Makosza; Dipl.-Chem. M. Ludwikow


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
203 KB
Volume
13
Category
Article
ISSN
0044-8249

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Kinetics of a photochromic reaction in a
โœ Krzysztof Janus; Juliusz Sworakowski; Andrzej Olszowski; Aleksandra Lewanowicz; ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 198 KB ๐Ÿ‘ 2 views

The kinetics of thermal cis-trans isomerisation of photochromic dibenzoazo 16-crown-4 ether was studied in several matrices (isooctane, polystyrene and pMMA samples fabricated in various ways) using UV-vis spectroscopy. The rate constants were found to be almost independent of the nature of the matr