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Crown cation complex effects. 16. Solvent dependence of the 15-crown-5 and 18-crown-6 equilibriums with sodium cation

✍ Scribed by Dishong, Dennis M.; Gokel, George W.

Book ID
120019767
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
278 KB
Volume
47
Category
Article
ISSN
0022-3263

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## Abstract Complexes of lanthanoid trinitrates Ln(NO~3~)~3~ with 15‐crown‐5 ether **1** (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd) and with 18‐crown‐6 ether **2** (Ln = La, Ce, Pr, Nd) having a 1:1 stoichiometry as well as 4:3 complexes with **2** (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd) have been synthesized and