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Crown-annelated p-phenylenediamine derivatives as electrochemical and fluorescence responsive chemosensors: synthesis via arene–ruthenium chemistry

✍ Scribed by Anthony J Pearson; Jiunn-Jye Hwang


Book ID
104230566
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
80 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


The synthesis of two crown annelated tetraalkyl-p-phenylenediamine derivatives, via sequential S N Ar reactions on (p-dichlorobenzene)RuCp cationic complexes, is described.


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Crown-annelated p-phenylenediamine deriv
✍ Anthony J Pearson; Jiunn-Jye Hwang 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 125 KB

Cyclic voltammetry studies on crown-annelated tetraalkyl-p-phenylenediamine derivatives, in the presence of metal mono-and dications, reveal high selectivity toward dications, of potential value for the development of electrochemical sensors.