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Crown-6-calix[4]arene-Capped Calix[4]pyrrole: An Ion-Pair Receptor for Solvent-Separated CsF Ions

โœ Scribed by Sessler, Jonathan L.; Kim, Sung Kuk; Gross, Dustin E.; Lee, Chang-Hee; Kim, Jong Seung; Lynch, Vincent M.

Book ID
120323844
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
652 KB
Volume
130
Category
Article
ISSN
0002-7863

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The straightforward synthesis of a C s symmetrical calix[6]arene possessing carboxylic acid groups as well as an ammonium arm is described. This calixarene can encapsulate ammonium ions through a highly selective recognition process thanks to the presence of an internal ion-paired cap that preorgani