✦ LIBER ✦

Crossed beam chemiluminescence

✍ Scribed by Ch. Ottinger; R.N. Zare

Book ID: 103010230
Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 502 KB
Volume: 5
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)85016-3

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✦ Synopsis

spectra from reactions of Ba and Ca with NO3 and NsO were observed and L6 bands were assigned to the BaOA 1.E -X lZ system for Ba+ NO2. From this. a lower limit of 5.74 eV (133 kcal/mole) is placed on the BaO ground state dissociation energy. Ba+ N20 bows large angle nonreactive scattering while Ba+ NO2 reacts at every collision (cross section 2 150 x 2). An electron jump mechanism is proposed.

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