Cross-quadratic terms involving modes of different symmetry in the nuclear potential of metalloporphyrins

✍ Scribed by Benjamin Scharf

• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 440 KB
• Volume: 99
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(83)87556-3

✦ Synopsis

The existence of crossquadratic termsinvolving modes of different symmetry in the nuclear potential of the excited elcstronic states corresponding to the visible and Soret WV) bands of metalloporphyrins is elucidated. The "intrastate" snd "interstarr" wurccs of thcsc terms are diccussed for various degees of mixing of the two lowest excited allowed ekctronic conf&urJtions.