Cross polarization magic-angle spinning NMR at cryogenic temperatures
โ Scribed by V Macho; R Kendrick; C.S Yannoni
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 420 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-2364
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๐ SIMILAR VOLUMES
In this publication a theoretical model is presented that deapproach and apply it to a system S(1)I N containing N abunscribes cross-polarization magic-angle spinning ( CPMAS ) dant I ร 1 2 spins that are coupled to a single spin with S ร NMR experiments on a spin system S ( 1 ) I N , consisting of
## Abstract The 13C chemical shifts of the CP/MAS NMR for ferrocene derivatives have been measured. Copyright ยฉ 2002 John Wiley & Sons, Ltd.
Thermodynamic aspects of cross polarization under fast magic angle sample spinning are studied. An extension of the static cross-polarization model is presented which applies to the "sidebands" ofthe Hartmann-Hahn condition. The cross-polarization process for the "sidebands" is not spin-energy conse
We have recently demonstrated that polarization transfer using an adiabatic passage through the Hartmann-Hahn condition (APHH-CP) by a variation of the radio-frequency amplitude can substantially improve the transfer efficiency over Hartmann-Hahn cross polarization. Here we show that APHH-CF' can be