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Cross-metathesis reaction. Generation of highly functionalized olefins from unsaturated alcohols

✍ Scribed by Janine Cossy; Samir BouzBouz; Amir H. Hoveyda

Book ID
108346851
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
152 KB
Volume
624
Category
Article
ISSN
0022-328X

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One-pot sequential cross-metathesis/hydride reduction: highly stereoselective synthesis of primary (E)-allylic alcohols from terminal olefins
✍ Tapas Paul; Gopal Sirasani; Rodrigo B. Andrade πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 French βš– 149 KB

Several di-and trisubstituted primary (E)-allylic alcohols have been prepared from the corresponding terminal olefins in a highly stereoselective manner (>20:1 E/Z) by sequencing olefin cross-metathesis (CM) with hydride reduction (DIBAL-H) in good yields utilizing only commercially available reagen