Cross-Metathesis of Propane and Methane: A Catalytic Reaction of CC Bond Cleavage of a Higher Alkane by Methane
✍ Scribed by Daravong Soulivong; Christophe Copéret; Jean Thivolle-Cazat; Jean-Marie Basset; Barry M. Maunders; Richard B. A. Pardy; Glenn J. Sunley
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 153 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The first examples of insertion of a CC bond of an alkyne into a C~carbene~C~__α__~ single bond of a carbene complex (CC~__α__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~MC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo CC~__α__~ insertion of