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Cross-metathesis, a versatile synthetic methodology for the construction of alkenyl phosphine oxides and bis-phosphine oxides

✍ Scribed by F. Bisaro; V. Gouverneur

Book ID: 104254394
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 100 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01842-2

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✦ Synopsis

Substituted vinyl and allyl phosphine oxides have been prepared by olefin cross-metathesis providing exclusive E olefin stereochemistry. The methodology has been successfully extended to the preparation of various bis-phosphine oxides.

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