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Cross-Coupling of (Z)-1,2-Bis(ethylseleno)ethene with the Grignard Reagents.

✍ Scribed by Alexander V. Martynov; Vladimir A. Potapov; Svetlana V. Amosova; Nataliya A. Makhaeva; Irina P. Beletskaya; Laszlo Hevesi

Book ID
101941726
Publisher
John Wiley and Sons
Year
2003
Weight
88 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

πŸ“œ SIMILAR VOLUMES

Stereospecific stille-coupling reaction
Stereospecific stille-coupling reaction of (Z)-1,2-bis(trimethylstannyll)ethenes with hypervalent iodonium salts
✍ Suk-Ku Kang; Yong-Tack Lee; Sang-Ho Lee πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 222 KB

The Stille coupling of (Z)-1,2-bis(trimethylstannyl)ethenes with hypervalent iodonium salts (1 equiv) proceeded stereospecifically in the presence of PdCI\_, (5 mol %) in DMF at room temperature to afford partially substituted (Z)-vinylstannanes under mild conditions. Alternatively, the use of 2 equ