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Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C−O Bond Activation

✍ Scribed by Li, Bi-Jie; Xu, Li; Wu, Zhen-Hua; Guan, Bing-Tao; Sun, Chang-Liang; Wang, Bi-Qin; Shi, Zhang-Jie

Book ID: 117991397
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 238 KB
Volume: 131
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja907281f

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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The nickel catalyzed cross-coupling of alkyl and alkenyl Grignard reagents with aryl nitrile derivatives affords good yields of the corresponding aryl alkanes or aryl alkenes via activation of the C CN bond. To prevent direct addition of the nucleophile to the nitrile group, the reactivity of the Gr