## Abstract For Abstract see ChemInform Abstract in Full Text.
Cross-Conjugated Oligo(enynes)
โ Scribed by Rik R. Tykwinski; Yuming Zhao
- Book ID
- 101939913
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 49 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
๐ SIMILAR VOLUMES
Additions of lower order and higher order mixed and homostannylcuprates, as well as the Cu(I) catalyzed additions of Bu3SnBBN(OMe)'Li +, Bu3SnAIEt 2, and Bu3SnMgMe to conjugated 1,3-enynes were investigated. Regioselective additions (> 90% of one isomer) of these bimetallic reagents to the alkyne mo
Donor (p-NMe 2 C 6 H 4 ) and acceptor (p-NO 2 C 6 H 4 ) substitution has been appended onto two different cross-conjugated enyne scaffolds and the electronic effects as a function of substitution have been evaluated. Interestingly, the observed electronic effects are quite dependent on the constitut