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Critical properties of ternary mixtures: Siloxane and perfluoromethylcyclohexane mixtures

✍ Scribed by Richard J. Sadus; Colin L. Young

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
247 KB
Volume
43
Category
Article
ISSN
0009-2509

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✦ Synopsis

The critical temperatures of some ternary siloxane mixtures are reported. The critical temperatures of binary perfluoromethylcyclohexane and siloxane mixtures were also measured. The results are compared to values calculated by solving the critical conditions from conformal solution theory using the one-fluid model, the ideal mixing equation and the Guggenheim equation of state. The agreement is good for mixtures of similar sized molecules whereas the agreement for dissimilar sized molecules is somewhat inadequate.

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