Critical point and vapor pressure of ionic fluids including NaCl and KCl

✍ Scribed by Kenneth S. Pitzer

• Book ID: 103022590
• Publisher: Elsevier Science
• Year: 1984
• Tongue: English
• Weight: 580 KB
• Volume: 105
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(84)80096-2

✦ Synopsis

The critical propertIes and the vapor and liquid densities of NaCl, KCI, and the prrmitcmodel ionic fluid are compared on a corresponding-states bask. In preparation for these comparisons the vapor density of NaCl at very high temperature is calculated from the aa~ate molecular parameters The very recent treatment of Gillan is adopted for the primitive model Th; liquid properties 01 KC1 and Nat3 follow corresponding states exactly but there is some discrepancy for the ion pair in the vapor. The differenrrs are &rearer for the primitive model but again the agreement is quite good for the liquid. Gitiul properties are reported for all three fluids.