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Critical considerations on the methods for evaluating kinetic parameters from nonisothermal experiments

✍ Scribed by C. Popescu; E. Segal

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
230 KB
Volume
30
Category
Article
ISSN
0538-8066

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✦ Synopsis

By surveying the most used methods for evaluating the kinetic parameters from nonisothermal experiments, a new classification scheme of the methods is proposed. For each method the number of principles and theoretical approximations required to derive the equation which grounds it, is considered as a comparison criterion. The methods are, finally, classified into classes of equivalence.

As a result of the analysis it is also suggested that the activation energy, as calculated from nonisothermal data, should be given as a range of values instead of a unique value.

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