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Critical conditions for formation of infinite networks in branched-chain polymers

✍ Scribed by Tanaka, Yoshio ;Kakiuchi, Hiroshi


Publisher
Wiley (John Wiley & Sons)
Year
1965
Tongue
English
Weight
663 KB
Volume
3
Category
Article
ISSN
0449-2951

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Polyethylene produced by a vanadium-based polymerization catalyst contains long-chain branching as determined by NMR and rheology, even though the polymer has very low levels of vinyl unsaturation. A new mechanism is proposed for the formation of the long-chain branching, which involves COH bond act