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Critical analysis of the graphical determination of hansen's solubility parameters for lightly crosslinked polymers

✍ Scribed by Edward T. Zellers; Daniel H. Anna; Robert Sulewski; Xiaorong Wei

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 956 KB
Volume: 62
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(19961219)62:12<2069::aid-app10>3.0.co;2-1

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✦ Synopsis

The most widely accepted method for determining Hansen's three-dimensional solubility parameters (3DSP) for crosslinked polymers entails graphically estimating the center of a spherical region in SDSP-coordinate space whose boundaries are defined in terms of the extent of swelling by solvents whose 3DSP values are known. In this article, the results of immersion tests performed a t 25OC with 53 solvents on each of four commercial polymeric glove materials are used to critically evaluate this method. Analyses reveal a number of serious shortcomings with respect to the reliability of 3DSP estimates obtained. In the context of modeling solubility or other measures of solvent-polymer compatability, it is recommended that alternative methods be sought for determining 3DSPs for crosslinked polymers.

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