Cr(III) Oxidation and Cr Toxicity in Cultures of the Manganese(II)-Oxidizing Pseudomonas putida Strain GB-1
β Scribed by Murray, Karen J.; Mozafarzadeh, Mylene L.; Tebo, Bradley M.
- Book ID
- 126485342
- Publisher
- Taylor and Francis Group
- Year
- 2005
- Tongue
- English
- Weight
- 445 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0149-0451
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The X-ray photoemission core level spectra of TlCr 5 Se 8 and Tl 0 2 Cr 5 Se 8 de5nitely exclude the oxidation of Tl(I) to Tl(III) when Tl is removed using a topotactic redox reaction between TlCr 5 Se 8 and bromine in acetonitrile. Alterations are only observed for the multiplett structure of the C
Magnetic measurements on Tl x Cr 5 Se 8 (04x41) reveal that stoichiometric TlCr 5 Se 8 is a three-dimensional antiferromagnet with a NeH el temperature T N of about 55 K. In contrast, samples with a reduced Tl content show highly unusual magnetic properties that are without precedent in the literatu