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Cr(III) in gahnite-containing transparent glass-ceramics: Influence of melting conditions and heat treatment on crystallization and spectroscopic properties

✍ Scribed by A. Kisilev; R. Reisfeld; A. Buch; M. Ish-Shalom


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
522 KB
Volume
129
Category
Article
ISSN
0009-2614

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✦ Synopsis


Transparent glass ceramics with Cr(III) were obtained by different thermal treatment of glass with composition (mol%) 73.6 SiO2, 11.8 A120,, 4.2 Li20, 7.0 ZnO, 1.6 TiO2, 1.5 ZrO2, 0.3 AszOs, 0.024 Cr203, melted under various conditions. Parallel measurements of X-ray diffraction, optical and EPR spectra reveal the different formation of gahnite from precursor glass or petal&e-like phase.