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Crazing of polymers in a supercritical carbon dioxide fluid

✍ Scribed by Trofimchuk, E. S.; Efimov, A. V.; Nikitin, L. N.; Nikonorova, N. I.; Dolgova, A. A.; Yarysheva, L. M.; Arzhakova, O. V.; Volynskii, A. L.; Bakeev, N. F.; Khokhlov, A. R.

Book ID
110160187
Publisher
Springer
Year
2009
Tongue
English
Weight
158 KB
Volume
428
Category
Article
ISSN
0012-5008

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## Abstract Radical polymerizations from third to fifth generation macromonomers were conducted in supercritical carbon dioxide (scCO~2~). It was found that all monomers were not soluble in such a medium, and reactions occurred in the CO~2~‐swollen monomer matrices. Despite the expected severe diff