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Cr3+ in kyanite: A new mechanism of thermally enhanced 2E decay

โœ Scribed by A.J. Wojtowicz; A. Lempicki


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
507 KB
Volume
46
Category
Article
ISSN
0022-2313

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The mechanisms of the reactions of diborane with ammonia have been investigated by ab initio molecular orbital methods. The activation barrier of the formation of aminoborane, H,&NHr, from the adduct, H,B : NHs, of borane and ammonia is high (over 40 kcal/mol), because it is a reaction essentially