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Cp*–-Ruthenium–Nickel-Based H2-Evolving Electrocatalysts as Bio-inspired Models of NiFe Hydrogenases

✍ Scribed by Sigolène Canaguier; Marc Fontecave; Vincent Artero

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 339 KB
Volume: 2011
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.201000944

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## Abstract Three new dinuclear nickel ruthenium complexes, namely [Ni(xbsms)Ru(__p__‐cymene)Cl]^+^, [Ni(emi)Ru(CO)~2~Cl~2~]^2–^ and [Ni(emi)Ru(__p__‐cymene)Cl]^–^ [H~2~xbsms = 1,2‐bis(4‐mercapto‐3,3‐dimethyl‐2‐thiabutyl)benzene, H~2~emi = __N__,__N′__‐ethylenebis(2‐mercaptoisobutyramide], have bee