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CoX2(NO)(PMe3)2 Complexes: an example of the influence of X (X = CI, Br, I, NO2) on the stereochemistry and electronic structure of the five-coordinate {CoNO}8 complexes

✍ Scribed by O. Alnaji; Y. Peres; M. Dartiguenave; F. Dahan; Y. Dartiguenave


Book ID
108328302
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
742 KB
Volume
114
Category
Article
ISSN
0020-1693

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Dichroic, Dinuclear μ2-(η2-NO)-Nitrosoan
✍ Christoph Krinninger; Christof Högg; Heinrich Nöth; Juan Carlos Gálvez Ruiz; Pet 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

## Abstract A series of unusual dinuclear μ~2~‐(η^2^‐__NO__)‐nitrosoaniline‐bridged complexes [{(CO)~3~Re(μ‐X)}~2~ONC~6~H~4~NR~2~] (X = Cl, Br, I; R = Me, Et) with dichroic properties have been synthesised by reaction of pentacarbonylhalogenorhenium(I) [(CO)~5~ReX] (X = Cl, Br, I) with the correspo