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Cover Picture: Triple Bond to Lead: Synthesis and Characterization of the Plumbylidyne Complex trans-[Br(PMe3)4MoPbC6H3-2,6-Trip2] (Angew. Chem. Int. Ed. 17/2004)

✍ Scribed by Alexander C. Filippou; Holger Rohde; Gregor Schnakenburg

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
20 KB
Volume
43
Category
Article
ISSN
0044-8249

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✦ Synopsis

The molybdenum–lead triple bond in the plumbylidyne complex shown is the first triple bond to a main‐group element of the sixth period. The small Mo–Pb bond and a linear coordination to the Pb atom are evident in the structure. Quantum‐chemical analysis with the electron localization function (reflected on the water) shows the electronic analogy between the plumbylidyne complex and Fischer carbene complexes. More about this can be found in the Communication by A. C. Filippou et al. on page 2243 ff.

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Titelbild: Triple Bond to Lead: Synthesi
Titelbild: Triple Bond to Lead: Synthesis and Characterization of the Plumbylidyne Complex trans-[Br(PMe3)4MoPbC6H3-2,6-Trip2] (Angew. Chem. 17/2004)
✍ Alexander C. Filippou; Holger Rohde; Gregor Schnakenburg 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 21 KB 👁 1 views

**Die Molybdän‐Blei‐Dreifachbindung** im abgebildeten Plumbylidin‐Komplex ist die erste Dreifachbindung zu einem Hauptgruppenelement der 6. Periode. Der kleine Mo‐Pb‐Abstand und die lineare Koordination am Bleiatom sind deutlich erkennbar. Quantenchemische Analysen mithilfe der Elektronenlokalisieru