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Cover Picture: Rhodium and Ruthenium Complexes of 1,1′-Bis(phosphetano)ferrocenes: Structural Characterisation and Catalytic Behaviour (Eur. J. Inorg. Chem. 14/2003)

✍ Scribed by Angela Marinetti; Francis Labrue; Bénédicte Pons; Sébastien Jus; Louis Ricard; Jean-Pierre Genêt

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 70 KB
Volume: 2003
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200390229

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✦ Synopsis

Abstract

The cover picture shows the X‐ray crystal structures of ruthenium and rhodium complexes of chiral 1,1′‐bis(phosphetano)ferrocenes. These diphosphanes rank among the ligands inducing excellent enantioselectivities in rhodium‐promoted hydrogenations of prochiral olefins. X‐ray crystal structures of their metal complexes afford information about their coordinating behaviour and preferred conformations in catalytically active species. Details are discussed in the article by A. Marinetti et al. on p. 2583 ff.

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